Synthesis of Hirsutene
C15H24
Principal investigator | Janine Cossy |
---|---|
Publication year | 1987 |
Synthesis type | Total |
Number of steps | 9 (linear) |
References |
Part 1 of 1
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Pd(OAc)2,
P(Oi-Pr)3
PhMe
Reflux, 20 h, 60%
Pd(OAc)2,
CH2N2
Et2O
0 °C, 30 min, 99%
PtO2,
NaOAc,
H2
1 atm
AcOH
RT, 20 h, 82%
KH
DME
-70 to 0 °C, 3 h, 71%
LiAlH4
Et2O
0 °C, 60 min, 90%
HCrO3Cl.Pyr
3 Å MS
CH2Cl2
RT, 4 h, 96%
Et3N
hν
MeCN
RT, 2.5 h, 58%
MeMgBr,
(Ph3P)2NiCl2
PhH
Reflux, 66 h, 35%