Smiles Rearrangement

Mechanism of the Smiles Rearrangement

Original publication	J. Chem. Soc.. 1931, 0, 3264.
Reviews	Chem. Soc. Rev.. 2008, 37, 2452. Org. React.. 1970, 18, 99.

Sample reactions

DMF

Reflux, 60 min, 87% (2 steps)