Saegusa-Ito Oxidation

Mechanism of the Saegusa-Ito Oxidation

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Sample reactions

Pd(OAc)2
MeCN
RT, 4 h, 84% (2 steps)


Pd(OAc)2
MeCN
RT, 3 h, 88% (2 steps)


O2, Pd(OAc)2
DMSO
RT, 18 h, 90% (2 steps)


O2, Pd(OAc)2
DMSO
RT, 18 h, 84% (2 steps)


Pd(OAc)2, 1,4-Benzoquinone
MeCN
RT, 6 h, 80% (2 steps)
"The yield was 89 % brsm."


Pd2(dba)3.CHCl3, Diallyl carbonate
MeCN
RT, 12 h, 90% (2 steps)


Pd(OAc)2
DMSO, MeCN
RT, 16 h, 82% (2 steps)


O2, Pd(OAc)2
DMSO
80 °C, 15 h, 91%


O2, Pd(OAc)2
DMSO
80 °C, 20 h, 75%


O2, Pd(OAc)2
DMSO
80 °C, 15 h, 91%


Pd(OAc)2
MeCN
RT, 33.5 h, 80% (2 steps)
