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Protecting Groups
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Named Reactions
Protecting Groups
Negishi Coupling
Mechanism of the Negishi Coupling
Original publication
J. Chem. Soc., Chem. Commun.. 1977, 0, 683.
Reviews
Acc. Chem. Res.. 1982, 15, 340.
Aldrichimica Acta. 2005, 38, 71.
Chem. Soc. Rev.. 2009, 38, 1598.
Tetrahedron. 1992, 48, 9577.
Sample reactions
info
Pd(PPh3)4
,
Me2Zn
THF
RT, 60 min, 84%
info
Pd(PPh3)4
,
t-BuLi
,
ZnCl2
Et2O
,
THF
-78 to 0 °C, 3.5 h, 67%