Keck Asymmetric Allylation

Schematic representation of the Keck Asymmetric Allylation.
Mechanism of the Keck Asymmetric Allylation
Mechanism of the Keck Asymmetric Allylation
Original publication
Tetrahedron Lett.. 1984, 25, 265.
Review
Chem. Rev.. 2003, 103, 276.
Sample reactions
info
intermediate structure
AllylSnBu3, (S)-BINOL, Ti(Oi-Pr)4
CH2Cl2
-78 to -20 °C, 36 h, 82%
intermediate structure