Criegee Reaction

Schematic representation of the Criegee Reaction.
Mechanism of the Criegee Reaction
Mechanism of the Criegee Reaction
Original publication
Review
Sample reactions
intermediate structure
Pb(OAc)4
AcOH, CH2Cl2
-20 °C, 10 min, 71% (2 steps)
intermediate structure
intermediate structure
Pb(OAc)4
PhH
20 min
intermediate structure
intermediate structure
Na2CO3, Pb(OAc)4
CH2Cl2
0 °C to RT, 2.5 h
intermediate structure
intermediate structure
Pb(OAc)4
MeOH, PhH
0 °C, 10 min, 97%
intermediate structure
intermediate structure
Pb(OAc)4
MeOH, PhH
0 °C, 5 min, 61% (2 steps)
intermediate structure
intermediate structure
Pb(OAc)4
CH2Cl2
-78 to 0 °C, 30 min, 69% (2 steps)
intermediate structure
intermediate structure
Pb(OAc)4
MeOH, PhH
0 °C, 10 min
intermediate structure