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Protecting Groups
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Named Reactions
Protecting Groups
Barton Decarboxylation
Mechanism of the Barton Decarboxylation
Original publication
J. Chem. Soc., Chem. Commun.. 1983, 0, 939.
Reviews
Heterocycles. 1989, 28, 951.
Tetrahedron. 2009, 65, 3563.
Sample reactions
info
DMAP
,
t-BuSH
hν
THF
Reflux, 90 min, 77% (2 steps)
info
BrCCl3
hν
RT to 90 °C, 65 min, 61% (2 steps)
info
DMAP
,
t-BuSH
PhMe
Reflux, 45 min, 82% (2 steps)