Synthesis of Centrohexaindane

Structure of Centrohexaindane

C41H24

Principal investigatorDietmar Kuck
Publication year1995
Synthesis typeTotal
Number of steps 6 (linear)
References
Part 1 of 1
intermediate structure
BnBr, KF, Celite
MeCN
75 °C, 18 h, 89%
intermediate structure
PPA
120 °C, 12-60 h, 91%
intermediate structure
Br2
CCl4
Reflux, 30 min, 93%
intermediate structure
Na2HPO4, KH2PO4, NaBr
DMSO
80-100 °C, 8 h, 79%
intermediate structure
PhLi
PhH, Et2O
40 °C, 6 h
intermediate structure
H3PO4
Xylene(s)
Reflux, 25-30 h, 40% (2 steps)
intermediate structure