Synthesis of Centrohexaindane

Structure of Centrohexaindane

C41H24

Principal investigatorDietmar Kuck
Publication year1995
Synthesis typeTotal
Number of steps 7 (linear)
References
Part 1 of 1
intermediate structure
BnBr, KF, Celite
MeCN
75 °C, 18 h, 89%
intermediate structure
LiAlH4
THF
Reflux, 4 h, 99%
intermediate structure
H3PO4
Xylene(s)
Reflux, ON, 92%
intermediate structure
Br2
CCl4
RT, 2 h
intermediate structure
AlBr3
PhH
RT to 50 °C, 7 d, 88% (2 steps)
intermediate structure
Br2
CCl4
Reflux, 3.5 h
intermediate structure
AlBr3
PhH
RT, 3-5 d, 57% (2 steps)
intermediate structure