Synthesis of Triquinacene

Structure of Triquinacene

C10H10

Principal investigatorPierre Deslongchamps
Publication year1973
Synthesis typeTotal
Number of steps 6 (linear)
References
Part 1 of 1
intermediate structure
NaN3, H2SO4
CF3CO2H
45-50 °C, 5 h, 35%
intermediate structure
MeOH
RT, 30 min
intermediate structure
HCl
Acetone, H2O
RT, 60 min
See the Aldol Addition
intermediate structure
LiAlH4
Et2O
Reflux, 3 h, 55% (3 steps)
intermediate structure
MsCl, Pyr
CH2Cl2
-30 to 0 °C, 3.5 d, 84%
intermediate structure
Al2O3
CH2Cl2
RT, 23 h, 57%
intermediate structure