Synthesis of Longifolene
C15H24
Principal investigator | Wolfgang Oppolzer |
---|---|
Publication year | 1978 |
Synthesis type | Total |
Number of steps | 10 (linear) |
References |
Part 1 of 1
+
Et3N
CHCl3
35 °C, 82%
ClCO2Bn
Pyr
5 °C, 8 h, 88%
PtO2,
H2
3 atm
AcOH
RT, 18 h, 96%
- i-Pr2NLi
- MeI
THF
-78 °C to RT, 2 h, 94%
MeLi
Et2O
48 °C, 3 h
SOCl2
Pyr
0 °C, 10 min, 80% (2 steps)