Tiffeneau-Demjanov Rearrangement

Schematic representation of the Tiffeneau-Demjanov Rearrangement.
Mechanism of the Tiffeneau-Demjanov Rearrangement
Mechanism of the Tiffeneau-Demjanov Rearrangement
Sample reactions
intermediate structure
NaNO2, NaOAc
AcOH
0 °C, , 80%
intermediate structure