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Protecting Groups
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Named Reactions
Protecting Groups
Overman Rearrangement
Mechanism of the Overman Rearrangement
Original publication
J. Am. Chem. Soc.. 1974, 96, 597.
Reviews
Acc. Chem. Res.. 1980, 13, 218.
Org. React.. 2005, 66, 1.
Sample reactions
info
Et3N
,
(CF3CO)2O
,
Cl3CCH2OH
CH2Cl2
0 °C to RT, 3.5 h, 87%
info
Na2CO3
o-Xylene
140 °C, 2.5 h, 58% (2 steps)