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Protecting Groups
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Named Reactions
Protecting Groups
Davis Asymmetric Hydroxylation
Mechanism of the Davis Asymmetric Hydroxylation
Original publication
J. Org. Chem.. 1986, 51, 2402.
J. Am. Chem. Soc.. 1990, 112, 6679.
Review
Chem. Rev.. 1992, 92, 919.
Sample reactions
info
i-Pr2NLi
THF
-78 to -35 °C, 70 min, 85%
info
TMS2NK
,
(+)-(Camphorsulfonyl)oxaziridine
HMPA
,
PhMe
,
THF
-78 °C, 2 h, 90 %